Comment on: Mass Fractions of Forty‐Six Major and Trace Elements,Including Rare Earth Elements,in Sediment and Soil Reference Materials Used in Environmental Studies. Fiket et al. (2017), Geostandards and Geoanalytical Research, 41, 123–135     

Vibor Roje 《Geostandards and Geoanalytical Research》2019,43(2):317-327

This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.  相似文献   

南海边缘海多金属结核与大洋多金属结核对比     

殷征欣  王海峰  韩金生  吕修亚  沈泽中  陈静  贺惠忠  谢安远  关瑶  董超 《吉林大学学报(地球科学版)》2019,49(1):261-277

本文通过系统对比分析前人研究成果,研究了南海边缘海多金属结核的成矿特征,结果表明：南海边缘海结核的矿物组成与大洋结核相似,均主要由锰相矿物和铁相矿物组成,其中锰相矿物主要为水羟锰矿和钡镁锰矿,铁相矿物主要以无定型铁氧化/氢氧化物形式存在,另外南海边缘海结核中含有大量硅酸盐矿物,表明在南海结核成矿过程中受到大量的陆源碎屑矿物混杂;相对于大洋主要经济成矿区的多金属结核,南海边缘海多金属结核中主要的经济元素如Mn、Cu、Co、Ni和Zn质量分数较低,而亲陆源性元素如Fe、Ti、P、Nb、Pb、Rb、Sc、Ta、Sr、Th和REY（REE和Y）等质量分数较高;南海边缘海多金属结核的元素地球化学特征和REE配分模式显示其为水成成因,并呈现更低的Mn/Fe值;同时南海边缘海结核也具有较快的平均生长速率及较高的δCe正异常,表明其生长在更为氧化的海水环境。虽然较快的沉积物沉积速率和动荡的海水环境影响了南海边缘海结核的成矿,但大量陆源物质进入海洋也为南海边缘海结核提供了丰富的成矿物质来源,便于南海边缘海结核的快速生长成矿。南海边缘海结核富集有Fe、Ti、Pb、Rb、Th和REY等金属元素,同样可以作为极具潜力的海洋矿产资源。南海边缘海多金属结核具有其独特的地球化学特征,与大洋多金属结核存在着明显差异。  相似文献   

Identification of the anomaly component using BEMD combined with PCA from element concentrations in the Tengchong tin belt,SW China   总被引：1，自引：0，他引：1  

Yongqing Chen  Lina Zhang  Binbin Zhao 《地学前缘(英文版)》2019,10(4):1561-1576

Concentration of elements or element groups in a geological body is the result of multiple stages of rockforming and ore-forming geological processes.An ore-forming element group can be identified by PCA(principal component analysis)and be separated into two components using BEMD(bi-dimensional empirical mode decomposition):(1)a high background component which represents the ore-forming background developed in rocks through various geological processes favorable for mineralization(i.e.magmatism,sedimentation and/or metamorphism);(2)the anomaly component which reflects the oreforming anomaly that is overprinted on the high background component developed during mineralization.Anomaly components are used to identify ore-finding targets more effectively than ore-forming element groups.Three steps of data analytical procedures are described in this paper; firstly,the application of PCA to establish the ore-forming element group;secondly,using BEMD on the o re-forming element group to identify the anomaly components created by different types of mineralization processes; and finally,identifying ore-finding targets based on the anomaly components.This method is applied to the Tengchong tin-polymetallic belt to delineate ore-finding targets,where four targets for Sn(W)and three targets for Pb-Zn-Ag-Fe polymetallic mineralization are identified and defined as new areas for further prospecting.It is shown that BEMD combined with PCA can be applied not only in extracting the anomaly component for delineating the ore-finding target,but also in extracting the residual component for identifying its high background zone favorable for mineralization from its oreforming element group.  相似文献   

Fracture grouting and geonails for soft soil tunnelling     

Y. M. Cheng  S. K. Au  H. Wong 《Geomechanics and Geoengineering》2019,14(2):99-117

To stabilise the tunnel faces and slopes in soft clay for the Airport Link construction in Australia, fracture grouting and glass fibre-reinforced plastic (GFRP) soil nails are proposed for the soil improvement as well as ease of handling. The compensation caused by the fracture grouting and the gain in strength due to consolidation as well as the geonail have stabilised the soft clay during construction. Only a small amount of ground settlement during soft clay box-jacking operation is generated so that the railway traffic above the embankment can be maintained without interference. The design method of the fracture grouting ground improvement study for this difficult project is discussed in this paper. Extensive laboratory and field tests were employed to verify the design assumptions and to fine-tune the ground improvement studies. The success of this project in poor ground conditions results from combined efforts of extensive field tests, an improved ground improvement design method and a realistic numerical analysis to assess the unstable/highly stressed zones for the placement of soil reinforcement.  相似文献   

深海管道钢的腐蚀疲劳裂纹扩展特性试验研究     

谭玉娜  余建星  余杨  王昭宇  王华昆  李修波 《中国海洋大学学报(自然科学版)》2021,(6):109-115,124

采用侧壁开槽型CT试样,分别在空气和3.5%NaCl溶液中进行腐蚀疲劳裂纹扩展试验,研究海底管道用钢X65在海水腐蚀环境下的腐蚀疲劳裂纹扩展特性。为保证试样既能满足腐蚀疲劳试验机的夹具要求,又可控制裂纹沿直线方向扩展,采用侧壁开槽技术对CT试样进行改进;利用有限元软件ABAQUS,建立三维模型,验证了对于侧壁开槽型CT试样,可以采用ASTM标准推荐的应力强度因子表达式对改进后CT试样开展数值计算。利用YYF-50腐蚀疲劳试验装置开展试验,试验结果表明:和惰性环境相比,腐蚀环境不仅会加速X65钢的裂纹扩展速率,还会降低腐蚀疲劳体系下裂纹扩展的门槛值;在腐蚀体系下存在裂纹扩展的稳定阶段,可采用Paris公式对其腐蚀疲劳裂纹扩展速率进行预测。  相似文献   

Fully coupled hydraulic fracture simulation using the improved element partition method     

Shujun Peng  Zhennan Zhang  Jianye Mou  Bing Zhao  Zhiyuan Liu  Jiading Wang 《国际地质力学数值与分析法杂志》2019,43(1):441-460

The improved element partition method (IEPM) is a newly developed fracture simulation approach. IEPM allows a fracture to run across an element without introducing extra degrees of freedom. It can also simulate any number of fractures in a prescribed mesh without remeshing. In this study, the IEPM is extended to hydraulic fracture simulation. First, the seepage and volumetric storage matrix of a cracked element are derived using virtual nodes (the intersection points of a crack with element edges). Subsequently, the fully coupled hydromechanical equation is derived for this cracked element. To eliminate the extra degrees of freedom (virtual nodal quantities), the water pressure and displacement of the virtual nodes are associated with their adjacent nodes through least squares interpolation. Finally, the fully coupled equation in terms of nodal quantities is obtained. The verification cases validate the method. By using this method, the field-scale hydraulic fracturing process is well simulated. The proposed approach is simple and efficient for field-scale hydraulic fracture simulation.  相似文献   

Undrained lower bound solutions for end bearing capacity of shallow circular piles in non-homogeneous and anisotropic clays     

Boonchai Ukritchon  Suraparb Keawsawasvong 《国际地质力学数值与分析法杂志》2020,44(5):596-632

The undrained bearing capacity of shallow circular piles in non-homogeneous and anisotropic clay is investigated by the lower bound (LB) finite element limit analysis (FELA) under two-dimensional (2D) axisymmetric condition using second-order cone programming, and the new solution of the problem is presented. Modified from the isotropic von Mises yield criterion, a cross-anisotropic undrained strength criterion of clays under the axisymmetric state of stress requiring three input shear strengths in triaxial compression, direct simple shear, and triaxial extension is employed in the 2D axisymmetric LB FELA. Parametric studies on the effects of pile embedment ratio, dimensionless strength gradient, anisotropic strength ratio, and pile roughness are investigated extensively, while the predicted failure mechanisms associated with these parameters are discussed and compared. Numerical results of undrained end bearing capacity of shallow circular piles are summarized in the form of design tables that are useful for design practice and represent a new contribution to the field of pile capacity considering the combined effects of undrained strength non-homogeneity and anisotropy.  相似文献   

Duluth Complex apatites: Age reference material for LA–ICP–MS‐based fission‐track dating     

Hideki Iwano  Tohru Danhara  Takashi Yuguchi  Takafumi Hirata  Masatsugu Ogasawara 《地学学报》2019,31(3):247-256

Anorthositic series apatites of the Duluth Complex, Minnesota, USA, have high spontaneous fission‐track densities of up to ~10⁷ cm^–2 and a homogeneous age of ~900 Ma, allowing high‐precision fission‐track dating based on LA–ICP–MS U analysis. Absolute fission‐track dating, track‐length measurement and chemical composition analysis were performed to evaluate a cooling history, which is essential for age reference materials. Preliminary inverse modelling for a sample with a shortened track‐length distribution yielded a monotonic cooling history from ~100°C at 925 Ma. The apatites incur an over‐etching problem when employing the commonly used etching protocol involving 5.5 M HNO₃.  相似文献   

晋西北地区表层土壤粒度与地球化学元素组成   总被引：1，自引：1，他引：0  

李继彦  周玲  刘益  张倩  蔡莹莹  张宝贵 《中国沙漠》2019,39(5):155-162

对晋西北地区表层土壤的物质组成进行研究，可以明确其物质来源、沉积环境及化学风化特征。选择区内表层土壤（深度0、10、20 cm）及其附近的河流沉积物，进行粒度和化学元素组成测试。结果表明：（1）晋西北地区表层土壤粒度组成以黏土和粉沙为主，且有自地表向下粗颗粒组分含量增加的趋势。（2）常量化学元素组成以SiO₂、Al₂O₃、CaO、Fe₂O₃为主，其余元素含量均较低。化学元素组成模式表明研究区内表层土壤物质与黄土高原腹地黄土有相同的物质源区，黄河河流沉积物对其贡献不大。（3）晋西北表层土壤的CIA值为52.70~57.89，平均54.06，说明它们的化学风化程度较低，处于早期的脱Na、Ca阶段。这是由于研究区地理位置比洛川更靠北，气温和降水量均低于洛川，降水量与兰州相差不大，但是年平均气温和年温差比兰州低。该研究明确了晋西北地区表层土壤的物质组成特征，为区域潜在沙漠化危害防治提供了数据支撑。  相似文献   

Quantitative prediction of discrete element models on complex loading paths     

Luc Sibille  Pascal Villard  Félix Darve  Rodaina Aboul Hosn 《国际地质力学数值与分析法杂志》2019,43(5):858-887

The ability of discrete element models to describe quantitatively (and not only qualitatively) the constitutive behaviour of a dense sand is assessed in this paper. Two kinds of 3D discrete models are considered. Both consider spheres as elementary particles. Nevertheless, the first model implements a contact law with rolling resistance whereas the second takes into account clumps made of two spheres. The discrete models are calibrated and validated from mechanical tests performed on a dense Hostun sand with a true triaxial apparatus. The calibration is carried out from axisymmetric drained compression tests, while the validation is discussed from monotonic and cyclic stress proportional loading paths and from a circular stress path in the deviatoric stress plane. The quality of the predictions of the discrete models are evaluated by comparison with the predictions given with advanced phenomenological constitutive relations, mainly an incrementally non-linear relation. Predictions given by the discrete models are remarkable, particularly when it is put in perspective with respect to the very few number of mechanical tests required for their calibration. However, these results and conclusions were reached in enabling conditions, and some limitations of such discrete models should be kept in mind.  相似文献